Method of manufacturing windshield using ion beam milling of glass substrate(s)

ABSTRACT

This invention relates to a method of making a laminated window such as a vehicle windshield. At least one of the two glass substrates of the window is ion beam milled prior to heat treatment and lamination. As a result, defects in the resulting window and/or haze may be reduced.

This application claims priority on U.S. Provisional Application No.60/340,248, filed Dec. 18, 2001, the disclosure of which is herebyincorporated herein by reference.

CROSS-REFERENCES TO RELATED APPLICATIONS

This application is related to commonly owned U.S. patent applicationSer. No. 09/703,709, filed Nov. 2, 2000, now U.S. Pat. No. 6,368,664.

BACKGROUND OF THE INVENTION

Vehicle windshields typically include a pair of bent glass substrateslaminated together via a polymer interlayer such as polyvinyl butyral(PVB). It is known that one of the two glass substrates may have acoating (e.g., low-E coating) thereon for solar control purposes such asreflecting IR and/or UV radiation, so that the vehicle interior can bemore comfortable in certain weather conditions.

Conventional windshields are made as follows. First and second flatglass substrates are provided, one of them having a low-E coatingsputtered thereon. The pair of glass substrates are washed and bookedtogether (i.e., stacked on one another), and then while booked are heatbent together into the desired windshield shape at a high temperature(s)(e.g., 8 minutes at about 600-625 degrees C.). The two bent glasssubstrates are then laminated together via the polymer interlayer toform the vehicle windshield.

Unfortunately, yields for such windshields are often as low as 70% (i.e.up to 30% may have to be thrown out). These rather low yields are causedby a number of factors, some of which are now described.

The glass substrates are typically made by the known float process whichis very efficient and effective. During the glass making process, SO₂ isoften used and tends to collect on the non-tin side of the glass. Thepresence of SO₂ deposits at the glass surface is not an immediateproblem, but upon heat treatment (HT) at the high glass bendingtemperatures mentioned above the presence of this material can causeblemishes or imperfections (e.g., sometimes known as fish-eyes) toappear in the final vehicle windshield. Other undesirable surfacedeposits which can occur on the glass surface and which may ultimatelycause significant blemishes or imperfections in a resulting windshieldinclude: suction cup marks made during handling, grease pencil marks,glove marks, spray paint marks, scratch(es), thin film(s) of impurities,stains, oil/grease, and/or the like. Again, one or more of theseundesirable deposits can result in windshield blemish(es) which maycause the windshield to have to be thrown away thereby resulting in lowyields at a significant cost to the windshield manufacturer.

In view of the above, a need in the art exists for improving yields invehicle windshield production and/or reducing the occurrence ofsignificant blemishes in vehicle windshields (e.g. fish-eyes). It is anobject of certain embodiments of this invention to fulfill one or moreof these needs, and/or other needs which may become apparent to theskilled artisan from the description herein.

BRIEF SUMMARY OF THE INVENTION

An object of this invention is to provide a method of making vehiclewindshields and/or other laminated windows in an improved manner.

Another object of this invention is to provide a method of makingvehicle windshields and/or other laminated windows in a manner so as toimprove production yields and/or reduce the occurrence of significantblemish(es) or imperfections therein.

Another object of this invention is to, in a method of making a vehiclewindshield or other laminated window, ion beam mill a surface of atleast one of the glass substrates prior to lamination in order to removecertain undesirable surface deposits. Advantageously, such ion beammilling has been found to improve yields and/or improve window quality.

Another object of this invention is to fulfill one or more of theabove-listed objects and/or needs.

Generally speaking, certain example embodiments of this inventionfulfill one or more of the above listed objects and/or needs byproviding a method of making a vehicle windshield, the methodcomprising: providing first and second glass substrates; on beam millingat least one surface of the first glass substrate so as to remove atleast 2 Å of glass from at least a portion of the first substrate andform an ion beam milled surface of the first substrate; sputtering acoating, including at least one infrared (IR) reflecting layer, on theion beam milled surface of the first substrate; and laminating the firstsubstrate with the coating thereon to the second substrate via a polymerinclusive interlayer so that the coating and the interlayer are providedbetween the first and second substrates.

Other example embodiments of this invention fulfill one or more of theabove listed objects and/or needs by providing a method of making alaminated window, the method comprising: providing first and secondglass substrates; ion beam milling at least one surface of the firstglass substrate so as to remove at least 2 Å of glass from at least aportion of the first substrate and form an ion beam milled surface ofthe first substrate; forming a coating on the ion beam milled surface ofthe first substrate; and laminating the first substrate with the coatingthereon to the second substrate via a polymer inclusive interlayer sothat the coating and the interlayer are provided between the first andsecond substrates.

Still other example embodiments of this invention fulfill one or more ofthe above-listed objects and/or needs by providing a vehicle windshieldcomprising: first and second glass substrates laminated to one anothervia a polymer inclusive interlayer; wherein at least one surface of thefirst glass substrate is ion beam milled; and wherein the windshield hasa visible transmittance of at least 70%.

Yet other example embodiments of this invention fulfill one or more ofthe above-listed objects and/or needs by providing a method of making avehicle windshield with reduced haze, the method comprising: ion beammilling a first substrate, laminating the first substrate to a secondsubstrate via an interlayer to form the windshield, and wherein the ionbeam milling causes haze in the windshield to be reduced by at least20%.

Still other example embodiments of this invention fulfill one or more ofthe above-listed objects by providing a method of making a window unit,the method comprising: providing first and second glass substrates; ionbeam milling at least one surface of the first glass substrate so as toremove at least 2 Å of glass from at least a portion of the firstsubstrate and form an ion beam milled surface of the first substrate;forming a coating on the ion beam milled surface of the first substrate;and coupling the first substrate with the coating thereon to the secondsubstrate so that the coating is provided between the first and secondsubstrates. In this regard, the window unit may be a vehicle windshield,an insulating glass (IG) window unit, or any other type of window unit.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross sectional view of a vehicle windshield according to anembodiment of this invention.

FIG. 2 is a cross sectional view of a vehicle windshield according toanother embodiment of this invention.

FIG. 3 is a flowchart illustrating certain steps carried out in making avehicle windshield according to any embodiment herein.

FIG. 4 is a graph (thickness of glass substrate removed by ion beammilling vs. windshield yield %) illustrating that ion beam millingimproves yields according to certain example embodiments of thisinvention.

FIG. 5 is a graph (ion beam scans vs. haze %) illustrating that ion beammilling reduces haze in resulting windshields in certain exampleembodiments of this invention.

FIG. 6 is a cross sectional view of a vehicle windshield or other windowaccording to an example embodiment of this invention.

FIG. 7 is a perspective view of an ion beam source which may be used inmilling according to an example embodiment of this invention.

FIG. 8 is a cross sectional view of the ion beam source of FIG. 7.

FIG. 9 is a schematic diagram illustrating ion beam milling of a glasssubstrate according to an example embodiment of this invention.

FIG. 10 is a flowchart illustrating certain steps taken in making avehicle windshield according to an example embodiment of this invention.

FIG. 11 is a side cross sectional view of a coated article according toanother embodiment of this invention.

FIG. 12 is a side cross sectional view of an insulating glass (IG)window unit according to another example embodiment of this invention.

DETAILED DESCRIPTION OF THE INVENTION

Referring now more particularly to the accompanying drawings in whichlike reference numerals indicate like parts/steps through the severalviews.

Certain example embodiments of this invention relate to a method ofmaking a vehicle windshield or other laminated window. In certainembodiments, one or both of the glass substrates is ion beam milled(i.e., in order to remove some of the glass from the substrate surface)prior to lamination. This ion beam milling has been found to reduce thelikelihood of significant blemishes in final products, thereby improvingyields, presumably because the ion beam milling acts to remove certainundesirable surface deposits that were present on the glass surfaceprior to the milling (e.g., SO₂, suction cup marks, grease pencil marks,stains, glove marks, spray paint marks, scratches, and/or the like). Byremoving such undesirable deposits from the glass surface prior to heattreatment (e.g., heat bending and/or thermal tempering), blemishesand/or defects arising from such deposits can be reduced and/oreliminated in the final product. The embodiments described herein areprovided for purposes of example only, and are not intended to belimiting unless specifically claimed.

Raw defects such as cutting oil, suction cup marks, or G-cor oil areproblematic as discussed above, but may often be picked up by opticalrobot detector(s) and are not a problematic as more difficult to detectsoft defects (e.g., thin films of impurities). It has been found thatthe ion beam milling of the instant invention is good at reducing oreliminating these tough to detect soft defects, thereby improving yieldsof the resulting products (e.g., vehicle windshields).

FIG. 1 is a side cross sectional view of a vehicle windshield accordingto an example embodiment of this invention. The windshield includesfirst and second bent glass substrates 1 and 3, respectively, a coating(e.g., low-E coating) 5 provided on interior glass substrate 1, and apolymer based interlayer 7 (e.g., including PVB (polyvinyl butyral) orany other suitable polymer interlayer material) for laminating the twosubstrates together as illustrated. In this particular embodiment, itcan be seen that coating 5 is provided on the interior glass substrate 1which is adjacent to the vehicle interior; and coating 5 is located soas to face the interlayer 7 and the opposing substrate 3 so that thecoating 5 is between the two substrates 1 and 3.

Substrates 1 and 3 are preferably glass (e.g., soda lime silica glass)made via any suitable process (e.g., float process). The glasssubstrates 1 and 3 may be clear or colored (e.g., green, grey, blue,etc.) in different embodiments of this invention. While the glasssubstrates/sheets 1 and 3 are illustrated as being bent in the FIG. 1embodiment, it is recognized that they may instead be flat in otherembodiments of this invention where flat windshields or flat windows aredesired. Polymer inclusive or polymer based interlayer 7 may include orbe of PVB in certain embodiments of this invention, or alternatively maybe of or include any other suitable polymer inclusive interlayermaterial in other embodiments of this invention.

Coating 5 may be any suitable solar control coating, including but notlimited to any suitable low-emissivity (low-E) coating that reflectsinfrared (IR) and/or ultraviolet (UV) radiation. For example, andwithout limitation, low-E coating 5 may be or comprise any of thecoatings described and/or illustrated in any of U.S. Pat. Nos.5,557,462, 5,770,321, 5,514,476, 5,376,455, 6,132,881, 6,059,909,4,898,789, 4,413,877, or 3,682,528, all of which are hereby incorporatedherein by reference. Alternatively, coating 5 may be or comprise any ofthe coatings described or illustrated in any of U.S. patent applicationSer. Nos. 09/794,224, 09/778,949, 09/793,406, or 09/797,903, all ofwhich are hereby incorporated herein by reference. In still furtheralternative embodiments of this invention, any other solar controlcoating may be used as coating 5. While coating 5 is illustrated asbeing on the surface of only substrate 1 in the FIG. 1 embodiment, thoseskilled in the art will recognize that another coating 5 could also beprovided on the interior surface of the other substrate 3 adjacent thePVB layer 7.

In certain embodiments of this invention, it has been found that ionbeam milling of substantially the entire surface S of substrate 1 priorto sputter deposition of coating 5 thereon, and thus prior to heattreatment and lamination, enables reduction and/or elimination ofcertain blemishes and/or defects in the final product, and/or can reduceundesirable haze in the final product. As will be described in moredetail below, impingement of an ion beam from an ion beam source(s) onthe surface S of substrate 1 causes a certain portion of the glass atthe substrate surface to be milled/sputtered off (i.e., removed). Theamount of glass removed from substrate 1 during the ion beam milling isa function of, for example, the ion energy used, angle of incidence ofthe ion beam on the substrate surface S, the speed that the substratepassed under the ion beam, the feedstock gas(es) used in the ion beamsource, the type of ion beam source used, and/or the type of glass beingmilled.

Good results (i.e., good reduction in defects and/or reduction of haze)occur when the ion beam milling: removes at least about 2 Å of glassfrom surface S of substrate 1, more preferably removes at least about 5Å of glass from surface S of substrate 1, even more preferably removesfrom about 5-500 Å of glass from surface S of substrate 1, still morepreferably from about 10-100 Å of glass from surface S of substrate 1,and most preferably from about 20-80 Å of glass from surface S ofsubstrate 1.

Glass substrates 1 and/or 3 may be made via the known float process inwhich a tin bath is utilized. It will thus be appreciated by thoseskilled in the art that as a result of forming the glass substrates 1and/or 3 on molten tin in certain exemplary embodiments, small amountsof tin or tin oxide may migrate into surface areas of the glass on theside of the glass that was in contact with the tin bath duringmanufacture (i.e., typically, float glass may have a tin oxideconcentration of 0.05% or more (wt.) in the first few microns below thesurface that was in contact with the tin bath). In this regard, incertain example non-limiting embodiments of this invention, surface S ofsubstrate 1 which is ion beam milled is the non-tin side/surface of thesubstrate 1 (i.e., the tin side of substrate 1 is adjacent/in thevehicle interior and faces away from the polymer based interlayer 7 inthe FIG. 1 embodiment).

While FIG. 1 illustrates only the non-tin surface S of substrate 1 beingion beam milled, it will be recognized that other ion beam milling maybe carried out in other embodiments of this invention. For example, incertain embodiments of this invention, both surface S of substrate 1 andthe surface of substrate 3 facing layer 7 may be ion beam milled asdescribed herein. In other embodiments of this invention, both surface Sof substrate 1 and the exterior surface of substrate 3 may be ion beammilled as described herein. Optionally, the tin-side surface ofsubstrate 1 (i.e., which faces the vehicle interior in the FIG. 1embodiment) may also be ion beam milled.

FIG. 2 is a side cross sectional view of a vehicle windshield accordingto another embodiment of this invention. The FIG. 2 embodiment issimilar to the FIG. 1 embodiment described above, except that thecoating 5 is provided on the exterior glass substrate 3 instead of onthe interior substrate 1. Thus, in this embodiment, the ion beam millingis performed on the non-tin side surface S of substrate 3 on whichcoating 5 is to be sputtered or otherwise deposited.

FIG. 3 is a flowchart illustrating steps taken in making a vehiclewindshield (or other laminated window) according to either the FIG. 1 orFIG. 2 embodiment(s) of this invention. In step A, a first glasssubstrate (flat or bent) is ion beam milled (e.g., in the FIG. 1embodiment at least surface S of substrate 1 is milled; while in theFIG. 2 embodiment at least surface S of substrate 3 is milled in thisstep). Thereafter, in step B a coating 5 is deposited (e.g., sputtered)onto the ion beam milled surface S of the first glass substrate. Then,in step C the ion beam milled and coated substrate is heat treated andbent into the desired windshield shape (either alone or together withanother substrate). During such heat bending, the glass substrate(s) areheated to temperature(s) of from 570-900 degrees C., more preferablyfrom 580-800 degrees C., for at least 2 minutes, more preferably for atleast 5 minutes, so as to enable glass bending and/or tempering. Afterthe ion beam milled and coated glass substrate has been heat bent, instep D it is laminated to another heat bent glass substrate via apolymer based interlayer (e.g., PVB inclusive layer 7) to form theresulting vehicle windshield.

FIG. 4 is a graph illustrating that ion beam milling of surface S of asubstrate (according to either the FIG. 1 or FIG. 2 embodiment(s))improves the yield % of the resulting vehicle windshield given a knowstandard of acceptance. As can be seen, even a small amount of ion beammilling removes sufficient undesirable deposits to improve yield to someextent, while additional milling (e.g., from 50-100 Å) significantlyimproves yield by further reducing the likelihood of productdefects/blemishes.

FIG. 5 is a graph illustrating that, surprisingly, certain amounts ofion beam milling of surface S of a substrate reduces the occurrence ofundesirable haze in the final windshield product. For the examplesmaking up FIG. 5, 150 sccm Ar feedstock gas was used in the ion beamsource at a pressure of 2.25 mTorr (four vacuum pumps operating), a 4015V potential was applied to the anode to achieve discharge current of1.782 Å, the glass substrate was moved at a linear velocity of 100inches/minute beneath the ion beam source, and the ion beam was incidenton the substrate at an angle θ of 45 degrees. The samples were exposedto different numbers of ion beam milling passes to see the results ofdifferent amounts of ion beam milling upon haze reduction. Aftermilling, a titanium oxide coating was applied to the milled substrate.As shown in FIG. 5, the samples exposed to four ion beam passes formilling had much less haze than the samples not ion beam milled. Freshlyproduced glass typically has a haze value of 0.05 to 0.08%, whilelong-time stored glass can have haze values of 2-10%. Thus, ion beammilling a surface of a glass substrate (tin side and/or non-tin side)can be used to reduce haze (e.g., to the values shown in FIG. 5). Theuse of ion beam milling according to certain embodiments of thisinvention may be used in combination with the FIGS. 1-2 embodimentsherein, or separate and independent thereof in other glass windowapplications.

With respect to haze, in certain embodiments of this invention, ion beammilling is performed on a glass substrate surface (see milling amountsabove with respect to glass removed) in order to reduce haze by at least10%, more preferably so as to reduce haze by at least 20%, and even morepreferably to reduce haze by at least 50%.

While many different types of coatings 5 may be used in either of theFIG. 1 or FIG. 2 embodiments of this invention, FIG. 6 illustrates anexample of one such coating. As illustrated, the multi-layer coating 5,including multiple IR reflecting Ag layers, is provided on the firstsubstrate (either substrate 1 or 3) over the ion beam milled surface Sthereof. The milled and coated substrate is then laminated to the othersubstrate (the other of 1 or 3) via polymer based interlayer 7. Thelow-E coating 5 of the FIG. 6 embodiment includes, from the glasssubstrate #1 outwardly, the following layers:

TABLE 1 (Example Coating Materials/Thicknesses; FIG. 6 Embodiment) LayerPreferred Range ( ) More Preferred ( ) Example (Å) TiO₂ 0-400  50-250100 Å Si_(x)N_(y) 0-400  50-250 170 Å NiCrO_(x) 5-100  10-50  18 Å Ag50-250   80-120 105 Å NiCrO_(x) 5-100  10-50  16 Å SnO₂  0-800 Å 500-850Å 650 Å Si_(x)N_(y) 0-800  50-250 170 Å NiCrO_(x) 5-100  10-50  18 Å Ag50-250   80-120 105 Å NiCrO_(x) 5-100  10-50  16 Å SnO₂  0-500 Å 100-300Å 150 Å Si₃N₄ 0-500 100-300 250 Å

In certain example embodiments of this invention, whether the FIG. 6coating 5 listed above, or some other coating is provided on the milledsubstrate, resulting vehicle windshields may be characterized by one ormore of the following parameters (as with other characteristics herein,these are non-limiting herein, unless specifically claimed):

TABLE 2 Example Color/Transmission After HT (Laminated Form)Characteristic General More Preferred T_(vis) (Ill. A, 2 deg.): >=70% >= 75% T_(vis) (Ill. C, 2 deg.): >= 70% >= 75% R_(g)Y (Ill. A, C; 2deg.): <= 15% <= 11% a*_(g) (Ill. A, C; 2°): −4.0 to +4.0 −1.0 to +1.0b*_(g) (Ill. A, C; 2°): −10.0 to +8.0 −8.0 to −2.0 R_(f)Y (Ill. A, C; 2deg.): <= 15% ≦11% a*_(f) (Ill. A, C; 2°): −6.0 to +6.0 −2.0 to +2.0b*_(f) (Ill. A, C; 2°): −5.0 to +5.0 −4.0 to +3.0 R_(solar): >= 24% >=28% Haze: <= 0.4 <= 0.3 T_(solar): <= 52% <= 48%

FIGS. 7-8 illustrate an example linear ion beam source 25 which may beused to ion beam mill a glass substrate(s) 1 and/or 3 herein. One ormore sources 25 may be used in different embodiments of this invention,depending upon the application. For example, when much milling isdesired, the glass substrate to be milled may be successively passedunder two or more different ion beam sources 25 which are in-line withone another. In alternative embodiments of this invention, only a singlesource 25 need be used. Ion beam source 25 includes gas/power inlet 26,anode 27, grounded cathode magnet portion 28, magnet poles 29, andinsulators 30. A 3 kV (or 5 kV or more) DC and/or AC power supply may beused for source 25 in some embodiments. The ion beam B from the sourcemay be focused or non-focused in different embodiments of thisinvention. Ion beam source 25 is based upon a known gridless ion sourcedesign. The linear source includes a linear shell (which is the cathodeand grounded) inside of which lies a concentric anode (which is at apositive potential). This geometry of cathode-anode and magnetic field33 gives rise to a closed drift condition. The anode layer ion sourcecan also work in a reactive mode. The source includes a metal housingwith a slit in a shape of a race track as shown in FIGS. 7-8. The hollowhousing is at ground potential. The anode electrode is situated withinthe cathode body (though electrically insulated) and is positioned justbelow the slit. The anode can be connected to a positive potential ashigh as 3,000 or more volts (V). Both electrodes may be water cooled incertain embodiments. Feedstock/precursor gases (e.g. Ar is preferred incertain ion beam milling embodiments, although other gases may insteadbe used in certain embodiments of this invention), described herein, arefed through the cavity between the anode and cathode. The linear ionsource also contains a labyrinth system that distributes the precursorgas fairly evenly along its length and which allows it to expand betweenthe anode-cathode space internally. The electrical energy then cracksthe gas to produce a plasma within the source. The ions (e.g., Ar+ ions)are expelled out at energies in the order of eVc-a/2 when the voltage isVc-a. The ion beam emanating from the slit is approximately uniform inthe longitudinal direction and has a Gaussian profile in the transversedirection. Exemplary ions 34 in ion beam B are shown in FIG. 8. A sourceas long as 1-4 meters may be made, although sources of different lengthsare anticipated in different embodiments of this invention. Electronlayer 35 completes the circuit thereby enabling the ion beam source tofunction properly. Still referring to FIGS. 7-8, a feedstock gas(es)(e.g. Ar and/or some other inert gas) may be fed through the ion beamsource via cavity 42 until it/they reach the area near slit 44 whereit/they is/are ionized. Other gas(es) (e.g., another inert gas oroxygen/nitrogen) may be used in addition to Ar in certain alternativeembodiments of this invention. The ion beam source of FIGS. 7-8 ismerely exemplary. Thus, in alternative embodiments of this invention, anion beam source device or apparatus as described and shown in FIGS. 1-3of U.S. Pat. No. 6,002,208 (hereby incorporated herein by reference inits entirety) may be used to ion beam mill substrate 1 and/or 3.

FIG. 9 illustrates a glass substrate (1 or 3) being ion beam milledaccording to an example embodiment of this invention using ion source25. As shown, the ion beam B from ion source 25 is incident upon thesurface S of the glass substrate at an angle θ. Beam incidence angle θ,between the ion beam and the substrate surface, may be from about 0-90degrees in different embodiments of this invention, more preferably fromabout 20-70 degrees, and most preferably from about 30-60 degrees.Surprisingly, it has been found that an angle of from 20-70 degrees,more preferably from 30-60 degrees, results in more efficient milling ofthe glass substrate surface S. It can also be seen that ion beam Bhitting the glass substrate causes a thickness amount “d” of glass to bemilled off of (i.e., removed from) the substrate. As stated above, theion beam B mills off at least about 2 Å of glass from the substrate,more preferably at least about 5 Å of glass from the substrate, evenmore preferably from about 5-500 Å of glass from the substrate, stillmore preferably from about 10-100 Å of glass from the substrate 1, andmost preferably from about 20-80 Å of glass from the substrate.

While ion beam milling herein may be used to make laminated windows(e.g., architectural windows, vehicle side windows or backlites), apreferred used is for vehicle windshields. FIG. 10 is a flowchartillustrating in detail a example non-limiting way in which a vehiclewindshield may be made using ion beam milling according to an embodimentof this invention (this process may be used to make the windshields ofany of FIGS. 1, 2 and 6). As illustrate, first and second glasssubstrates are provided (i.e., substrate #1 and substrate #2). As forthe first substrate, it optionally may be washed (step 101). At leastone surface of the first substrate is then ion beam milled as shown inFIG. 9 (step 102). A coating 5 is then sputtered onto the ion beammilled surface S of the first substrate (step 103). Optionally, bothsurfaces of the substrate may be ion beam milled. The coating 5 may be alow-E coating, or any other suitable solar control coating. The ion beammilled and coated first substrate is then cut into the shape to be usedin a windshield (step 104). It is then, optionally, seamed, washed anddried (step 105). Meanwhile, a second substrate is cut to size (step106) and optionally may be seamed, washed and dried (step 107). Thesecond substrate may or may not be ion beam milled (one or both surfacesthereof) in different embodiments of this invention. After bothsubstrates have been cut to size, they are booked with separator powdertherebetween (step 108). They are then heat treated and bent into thedesired windshield shape (step 109), and laminated together via apolymer based interlayer 7 (step 110). The resulting windshield may thenbe installed in a vehicle window frame (step 111). This detailed processis provided for purpose of example only, and is not intended to belimiting unless specifically claimed.

FIG. 11 is a cross sectional view of a coated article (e.g., vehiclewindshield or other window) according to another embodiment of thisinvention. This embodiment is similar to that of FIG. 2 described above,except that an additional coating 5 a is provided on the side ofsubstrate 3 opposite coating 5. Coating 5 may be as described above,while coating 5 a on the other side (e.g., the exterior side) ofsubstrate 3 may be of or include diamond-like carbon (DLC) or any othersuitable coating that may be hydrophobic (contact angle >=70 degrees),hydrophillic (contact angle <=15 degrees), and/or scratch resistant. Incertain embodiments, additional coating 5 a may even provide IR and/orUV reflection functionality. Since one of coatings 5 and 5 a in the FIG.11 embodiment is formed on the tin side of the glass substrate 3, ionbeam milling is used to remove much tin from the tin side of the glasssubstrate in order to improve yields and/or opticalcharacteristics/durability of the resulting product. In the FIG. 11embodiment, both sides of the glass substrate 3 may be ion beam milledas described herein, or alternatively only the tin side of the substratemay be ion beam milled as described herein. In still farther alternativeembodiments (applicable to IG units and vehicle windshields), coating 5may be provided on the interior surface of one of the substrates whilethe additional coating 5 a is provided on the exterior surface of theother substrate.

While the aforesaid embodiments are directed primarily toward laminatedwindows, this invention is not so limited unless specifically claimed.In certain alternative embodiments of this invention, the ion beammilling may be used in the context of insulating glass (IG) window unitswhere the two glass substrate are spaced apart from one another via atleast one spacer and an air/gas gap (see FIG. 12). In such IG windowunit embodiments, a surface of at least one of the substrates to receivea coating 5 (e.g., any of the coatings mentioned above) is ion beammilled as discussed herein.

Certain terms are prevalently used in the glass coating art,particularly when defining the properties and solar managementcharacteristics of coated glass. Such terms are used herein inaccordance with their well known meaning. For example, as used herein:

Intensity of reflected visible wavelength light, i.e. “reflectance” isdefined by its percentage and is reported as R_(x)Y or R_(x) (i.e. the Yvalue cited below in ASTM E-308-85), wherein “X” is either “G” for glassside or “F” for film side. “Glass side” (e.g. “G”) means, as viewed fromthe side of the glass substrate opposite that on which the coatingresides, while “film side” (i.e. “F”) means, as viewed from the side ofthe glass substrate on which the coating resides. Color characteristicsare measured and reported herein using the CIE LAB 1976 a*, b*coordinates and scale.

The terms “emissivity” (or emittance) and “transmittance” are wellunderstood in the art and are used herein according to their well knownmeaning. Thus, for example, the term “transmittance” herein means solartransmittance, which is made up of visible light transmittance (TY ofT_(vis)), infrared energy transmittance (T_(IR)), and ultraviolet lighttransmittance (T_(uv)). Total solar energy transmittance (TS orT_(solar)) can be characterized as a weighted average of these othervalues. With respect to these transmittances, visible transmittance maybe characterized for architectural purposes by the standard IlluminantC, 2 degree technique; while visible transmittance may be characterizedfor automotive purposes by the standard Ill. A 2 degree technique (forthese techniques, see for example ASTM E-308-95). For purposes ofemissivity a particular infrared range (i.e. 2,500-40,000 nm) isemployed.

The term R_(solar) refers to total solar energy reflectance (glass sideherein), and is a weighted average of IR reflectance, visiblereflectance, and UV reflectance. This term may be calculated inaccordance with the known DIN 410 and ISO 13837 (12/98) Table 1, p. 22for automotive applications, and the known ASHRAE 142 standard forarchitectural applications.

“Haze.” Light diffused in many directions causes a loss in contrast. Theterm “haze” is defined herein in accordance with ASTM D 1003 whichdefines haze as that percentage of light which in passing throughdeviates from the incident beam greater than 2.5 degrees on the average.

“Haze” may be measured herein by a Byk Gardner haze meter (all hazevalues herein are measured by such a haze meter and are unitless).

Another term employed herein is “sheet resistance”. Sheet resistance(R_(s)) is a well known term in the art and is used herein in accordancewith its well known meaning. It is here reported in ohms per squareunits. Generally speaking, this term refers to the resistance in ohmsfor any square of a layer system on a glass substrate to an electriccurrent passed through the layer system. Sheet resistance is anindication of how well the layer or layer system is reflecting infraredenergy, and is thus often used along with emissivity as a measure ofthis characteristic. “Sheet resistance” may for example be convenientlymeasured by using a 4-point probe ohmmeter, such as a dispensable4-point resistivity probe with a Magnetron Instruments Corp. head, ModelM-800 produced by Signatone Corp. of Santa Clara, Calif. Coatings 5herein may have a sheet resistance of less than or equal to 10 ohms/sq.,more preferably less than or equal to 5 ohms/sq.

While the invention has been described in connection with what ispresently considered to be the most practical and preferred embodiment,it is to be understood that the invention is not to be limited to thedisclosed embodiments, but on the contrary, is intended to cover variousmodifications and equivalent arrangements included within the spirit andscope of the appended claims.

What is claimed is:
 1. A method of making a vehicle windshield, themethod comprising: providing first and second glass substrates, andmaking at least the first substrate via a float process utilizing a tinbath so as to cause the first substrate to have a tin surface and anon-tin surface ion beam milling the non-tin surface of the first glasssubstrate so as to remove at least 2 Å of glass from at least a portionof the first substrate and form an ion beam milled surface of the firstsubstrate; sputtering a coating, including at least one infrared (IR)reflecting layer, on the ion beam milled surface of the first substrate;and laminating the first substrate with the coating thereon to thesecond substrate via a polymer inclusive interlayer so that the coatingand the interlayer are provided between the first and second substrates.2. The method of claim 1, wherein the IR reflecting layer comprisessilver (Ag).
 3. The method of claim 1, wherein the coating comprises atleast first and second IR reflecting layers comprising Ag.
 4. The methodof claim 3, wherein the coating further comprises: a first dielectriclayer provided between the first substrate and the first IR reflectinglayer comprising Ag, a second dielectric layer between the first andsecond IR reflecting layers, and a third dielectric layer between thesecond IR reflecting layer comprising Ag and the polymer inclusiveinterlayer.
 5. The method of claim 1, wherein said ion beam millingremoves at least 5 Å of glass from the first substrate.
 6. The method ofclaim 5, wherein said ion beam milling removes from 10-100 Å of glassfrom the first substrate.
 7. The method of claim 1, wherein the polymerinclusive interlayer comprises polyvinyl butyral (PVB).
 8. The method ofclaim 1, wherein the windshield is made so as to have at least one ofthe following characteristics: visible transmittance (I11. A, 2deg.): >= 75% haze: <= 0.4%.


9. The method of claim 1, wherein the windshield is made so as to haveat least one of the following characteristics: visible transmittance(I11. A, 2 deg.): >= 75% haze: <= 0.3%.


10. The method of claim 1, wherein the coating has a sheet resistance(R_(s)) of less than or equal to 10 ohms/sq.
 11. The method of claim 10,wherein the coating has a sheet resistance (R_(s)) of less than or equalto 5 ohms/sq.
 12. The method of claim 1, further comprising ion beammilling at least one surface of the second substrate prior to thelaminating.
 13. The method of claim 1, further comprising: after saidsputtering and prior to said laminating, heat bending said firstsubstrate with the coating thereon into a desired windshield shape. 14.The method of claim 1, wherein the ion beam milling reduces haze in thewindshield by at least about 20%.
 15. The method of claim 1, wherein theion beam milling comprises directing an ion beam at the surface of thefirst substrate so that the ion beam is incident upon the surface of thefirst substrate so as to form an angle θ with first substrate of from20-70 degrees.
 16. The method of claim 1, wherein the ion beam millingcomprises directing an ion beam at the first substrate so that the ionbeam is incident upon the first substrate in order to form an angle θwith the substrate of from 30-60 degrees.
 17. A method of making alaminated window, the method comprising: providing first and secondglass substrates; ion beam milling at least one surface of the firstglass substrate so as to remove at least 2 Å of glass from at least aportion of the first substrate and form an ion beam milled surface ofthe first substrate; sputtering a multi-layer coating, including atleast one IR reflecting layer comprising silver between at least firstand second dielectric layers, on the ion beam milled surface of thefirst substrate; laminating the first substrate with the coating thereonto the second substrate via a polymer inclusive interlayer so that thecoating and the interlayer are provided between the first and secondsubstrates; and wherein said ion beam milling reduces haze in theresulting window by at least 10%.
 18. The method of claim 17, whereinthe ion beam milling comprises directing an ion beam at the surface ofthe first substrate so that the ion beam is incident upon the surface ofthe first substrate so as to form an angle Å with first substrate offrom 20-70 degrees.
 19. The method of claim 17, wherein the ion beammilling comprises directing an ion beam at the first substrate so thatthe ion beam is incident upon the first substrate in order to form anangle Å with the substrate of from 30-60 degrees.
 20. The method ofclaim 17, wherein the coating comprises first and second layerscomprising Ag.
 21. The method of claim 17, wherein said ion beam millingremoves at least 5 Å of glass from the first substrate.
 22. The methodof claim 21, wherein said ion beam milling removes from 10-100 Å ofglass from the first substrate.
 23. The method of claim 17, wherein thewindow has a visible transmittance of at least 70%.
 24. The method ofclaim 23, wherein the window has a visible transmittance of at least75%.
 25. The method of claim 17, wherein the window comprises a vehiclewindshield.
 26. The method of claim 17, wherein the window has haze of<=0.4%.
 27. The method of claim 26, wherein the window has haze of<=0.3%.
 28. The method of claim 17, wherein the coating has a sheetresistance (R_(s)) of less than or equal to 5 ohms/sq.
 29. The method ofclaim 17, further comprising: after said forming and prior to saidlaminating, heat bending said first substrate with the coating thereon.30. The method of claim 17, wherein the ion beam milling reduces haze inthe window by at least about 20%.
 31. The method of claim 17, whereinthe ion beam milling comprises ion beam milling substantially the entireone surface of the first substrate.
 32. A method of making a vehiclewindshield with reduced haze, the method comprising: ion beam milling afirst substrate, sputtering a multi-layer coating including at least anIR reflecting layer comprising silver between at least first and seconddielectric layers onto a ion beam milled surface of the first substrate;laminating the first substrate to a second substrate via an interlayerto form the windshield, and wherein the ion beam milling causes haze inthe windshield to be reduced by at least 20%.
 33. The method of claim32, wherein the ion beam milling causes haze in the windshield to bereduced by at least 50%.
 34. A method of making a window unit, themethod comprising: providing first and second glass substrates; ion beammilling at least one surface of the first glass substrate so as toremove at least 2 Å of glass from at least a portion of the firstsubstrate and form an ion beam milled surface of the first substrate;sputtering a multi-layer coating on the ion beam milled surface of thefirst substrate; and coupling the first substrate with the coatingthereon to the second substrate so that the coating is provided betweenthe first and second substrates.
 35. The method of claim 34, wherein theion beam milling comprises directing an ion beam at the surface of thefirst substrate so that the ion beam is incident upon the surface of thefirst substrate so as to form an angle Å with first substrate of from20-70 degrees.
 36. The method of claim 34, wherein said ion beam millingremoves at least 5 Å of glass from the first substrate.
 37. The methodof claim 34, wherein said ion beam milling removes from 10-100 Å ofglass from the first substrate.
 38. The method of claim 34, wherein thewindow has a visible transmittance of at least 70%.
 39. The method ofclaim 34, wherein the window unit comprises one of a vehicle windshieldand an insulating glass (IG) unit.
 40. The method of claim 39, furthercomprising another coating provided on either the first or secondsubstrate, wherein the another coating is not provided on the ion beammilled surface.
 41. The method of claim 40, wherein the another coatingcomprises diamond-like carbon (DLC).
 42. A method of making aninsulating glass (IG) window unit, the method comprising: providingfirst and second glass substrates; ion beam milling at least one surfaceof the first glass substrate so as to remove at least 2 Å of glass fromat least a portion of the first substrate and form an ion beam milledsurface of the first substrate; forming a coating on the ion beam milledsurface of the first substrate; and coupling the first substrate withthe coating thereon to the second substrate via at least one spacer sothat the coating is provided between the first and second substrates andthe substrate are spaced apart with a space therebetween.
 43. The methodof claim 42, wherein the space is at least one of: filled with gas, andevacuated so as to be at a pressure less than atmospheric pressure. 44.The method of claim 42, wherein the ion beam milling comprises directingan ion beam at the surface of the first substrate so that the ion beamis incident upon the surface of the first substrate so as to form anangle Å with first substrate of from 20-70 degrees.
 45. The method ofclaim 42, wherein said ion beam milling removes at least 5 Å of glassfrom the first substrate.
 46. The method of claim 42, wherein said ionbeam milling removes from 10-100 Å of glass from the first substrate.